Organic Semiconductors Based on [2.2]Paracyclophanes and Porphyrins as Hole Transport Materials in Perovskite Solar Cells

Author:   Steffen Andreas Otterbach
Publisher:   Logos Verlag Berlin GmbH
Volume:   102
ISBN:  

9783832557096


Pages:   248
Publication Date:   18 August 2023
Format:   Paperback
Availability:   In Print   Availability explained
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Organic Semiconductors Based on [2.2]Paracyclophanes and Porphyrins as Hole Transport Materials in Perovskite Solar Cells


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Overview

Solar power has become a promising renewable energy source, with research increasing solar cell efficiency (PCE) from under 1 % to over 25 %. Perovskite solar cells (PSCs) show great potential due to their efficient excitation in the perovskite layer. However, hole transport layers (HTLs) have hindered achieving higher efficiencies. This thesis explores various organic hole transport materials (HTMs) to substitute spiro-OMeTAD, a commonly used but tedious and energyintensive HTL. [2.2]Paracyclophane (PCP) served as the core structure, yielding promising results with different pseudo-parasubstituted HTMs achieving up to 8.4 % PCE. Increasing the number of substituents to four led to an increased PCE of 11.0 %. Furthermore, 17 different porphyrins were synthesized, and tetraphenylethene (TPE) was introduced to study various substitution patterns’ influence on properties. The described materials displayed a wide range of HOMO energy levels suitable for perovskite solar cell applications.

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Author:   Steffen Andreas Otterbach
Publisher:   Logos Verlag Berlin GmbH
Imprint:   Logos Verlag Berlin GmbH
Volume:   102
ISBN:  

9783832557096


ISBN 10:   3832557091
Pages:   248
Publication Date:   18 August 2023
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   In Print   Availability explained
This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us.

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