Overview

During recent years a high level of interest has been maintained in the kinetics and mechanisms of inorganic compounds in solution, and there has also been a notable upsurge of literature concerned with reaction mechanisms of organo­ transition metal compounds. The reviews of the primary literature previously provided by ""Inorganic Reaction Mechanisms"" (Royal Society of Chemistry) and ""Reaction Mechanisms in Inorganic Chemistry"" in ""MTP International Re­ views of Science"" (Butterworths) continue to be of considerable value to those concerned with mechanistic studies, and it is unfortunate they are no longer published. The objective of the present series is to provide a continuing critical review of literature dealing with mechanisms of inorganic and organometallic reactions in solution. The scope of potentially relevant work is very large, particularly in the field of organotransition metal chemistry, and papers for inclusion have been chosen that specifically probe mechanistic aspects, rather than those of a prep­ arative nature. This volume covers the literature published during the period July 1979 to December 1980 inclusive. Material is arranged basically by type of reaction and type of compound along generally accepted lines. Numerical data are usually reported in the units used by the original authors, though the units of some results have been converted in order to make comparisons.

Full Product Details

Author:   M. Twigg
Publisher:   Springer-Verlag New York Inc.
Imprint:   Springer-Verlag New York Inc.
Edition:   Softcover reprint of the original 1st ed. 1983
Dimensions:   Width: 15.20cm , Height: 2.10cm , Length: 22.90cm
Weight:   0.572kg
ISBN:  

9781461574125

ISBN 10:   1461574129
Pages:   373
Publication Date:   22 June 2012
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   Manufactured on demand  
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Table of Contents

1. Electron Transfer Reactions.- 1. General Redox Processes and Reactions between Two Complexes.- 2. Metal-Ion-Ligand Redox Reactions.- 2. Substitution and Related Reactions.- 3. Reactions of Compounds of the Nonmetallic Elements.- 4. Substitution Reactions of Inert Metal Complexes— Coordination Numbers 4 and 5.- 5. Substitution Reactions of Inert Metal Complexes—Coordination Numbers 6 and Above.- 6. Substitution Reactions of Labile Metal Complexes.- 3. Reactions of Organometallic Compounds.- 7. Metal-Alkyl Bond Fission and Formation.- 8. Substitution, Oxidative Addition–Reductive Elimination, and Migration–Insertion Reactions.- 9. Rearrangements, Intramolecular Exchanges, and Isomerization of Organometallic Compounds.- 10. Reactivity of Coordinated Hydrocarbons.- 11. Homogeneous Catalysis of Organic Reactions by Complexes of Metal Ions.- References.- Author Index.- General Subject Index.

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