Overview

Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.

Full Product Details

Author:   Gernot Frenking
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   Softcover reprint of hardcover 1st ed. 2005
Volume:   12
Dimensions:   Width: 15.50cm , Height: 1.40cm , Length: 23.50cm
Weight:   0.454kg
ISBN:  

9783642062513

ISBN 10:   3642062512
Pages:   266
Publication Date:   13 November 2010
Audience:   Professional and scholarly ,  Professional & Vocational ,  Postgraduate, Research & Scholarly
Format:   Paperback
Publisher's Status:   Active
Availability:   Out of print, replaced by POD  
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Table of Contents

D.G. Musaev, K. Morokuma: Transition Metal Catalyzed s-Bond Activation and Formation Reactions.- S. Sakaki: Theoretical Studies of C-H s-Bond Activation and Related Reactions by Transition-Metal Complexes.- G. Drudis-Solé, G. Ujaque, F. Maseras and A. Lledós: Enantioselectivity in the Dihydroxylation of Alkenes by Osmium Complexes.- D.V. Deubel, C. Loschen and G. Frenking: Organometallacycles as Intermediates in Oxygen-Transfer Reactions. Reality or Fiction?.- A. Michalak, T. Ziegler: Late Transition Metals as Homo- and Co-Polymerization Catalysts.- S. Tobisch: Co-Oligomerization of 1,3-Butadiene and Ethylene Promoted by Zerovalent ‘Bare’Nickel Complexes.- V. Staemmler: The Cluster Approach for the Adsorption of Small Molecules on Oxide Surfaces

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