The Quantum Theory of Unimolecular Reactions

Author:   H. O. Pritchard
Publisher:   Cambridge University Press
ISBN:  

9780511735837


Publication Date:   04 August 2010
Format:   Undefined
Availability:   Available To Order   Availability explained
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The Quantum Theory of Unimolecular Reactions


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Overview

When this book was first published in 1984, the discovery of laser-induced mutliphoton chemical reactions had led to a resurgence of interest in the theory of unimolecular reactions. Attempts to explain these phenomena had been built on a very imperfectly understood theory of thermal unimolecular reactions. In this book, Professor Pritchard presents a treatment that dissects the unimolecular reaction process into a sequence of distinct phases, so that the assumptions of the theory can be clearly seen, and confusion over the theory avoided. As such it provides a self-consistent foundation upon which to begin to treat these phenomena. Postgraduate students and research workers in physical chemistry will find this an invaluable textbook on a topic that has suddenly become of primary importance.

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Author:   H. O. Pritchard
Publisher:   Cambridge University Press
Imprint:   Cambridge University Press (Virtual Publishing)
ISBN:  

9780511735837


ISBN 10:   0511735839
Publication Date:   04 August 2010
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Undefined
Publisher's Status:   Active
Availability:   Available To Order   Availability explained
We have confirmation that this item is in stock with the supplier. It will be ordered in for you and dispatched immediately.

Table of Contents

1. The observed properties of thermal unimolecular reactions; 2. The master equation for internal relaxation in molecules; 3. Reaction as a perturbation of the internal relaxtion; 4. The specific rate function k(E) as an inverse Laplace transform; 5. Unimolecular fall-off in strong collision systems; 6. A molecular dynamic approach to specific rate functions; 7. Building in the randomisation processes; 8. Weak collision processes; 9. How well does it all work?; Appendix.

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