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Author:   R. Ugo
Publisher:   Springer
Imprint:   Kluwer Academic Publishers
Edition:   1977 ed.
Volume:   3
Weight:   0.610kg
ISBN:  

9789027707864

ISBN 10:   9027707863
Pages:   249
Publication Date:   31 December 1977
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Out of stock  
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Table of Contents

of Volume 3.- Transition Metal Complexes as Catalysts for the Addition of Oxygen to Reactive Organic Substrates.- 1. Introduction.- 2. Structure and Bonding in Dioxygen Complexes.- 3. Properties of Coordinated Dioxygen.- 4. Formation and Stability of Dioxygen Complexes.- 5. Transfer of Coordinated Dioxygen to Reactive Substrates.- 6. Oxidation of Coordinated Ligands.- 7. Catalytic Oxidation Reactions.- 8. Catalytic Oxidation of Phosphines to Phosphine Oxides.- 9. Oxidation of Arsines to Arsine Oxides.- 10. Oxidation of Sulfides and Sulfoxides.- 11. Oxidation of Nitrogen Compounds.- 12. Carbon Monoxide.- 13. Aldehydes.- 14. Ketones.- 15. Alcohols.- 16. Oxidation of Olefins.- 17. Concluding Remarks.- 18. References.- Structure and Electronic Relations Between Molecular Clusters and Small Particles: An Essay to the Understanding of Very Dispersed Metals.- 1. Introduction.- 2. An Analysis of Size Range: A method of Finding an Overlap Between Very Small Particles and Molecular Clusters.- 3. Characterisation of Very Small Particles and of Molecular Clusters.- 4. Geometric Aspects of the Relation Between Very Small Particles and Molecular Clusters.- 5. Electronic Structures of Molecular Clusters and of Very Small Particles.- 6. Metal—Metal Bond Characteristics in Very Small Particles and Molecular Clusters.- 7. Electronic Aspects.- 8. Conclusion.- 9. References.- Asymmetric Hydrosilylation by Means of Homogeneous Catalysts with Chiral Ligands.- 1. Introduction.- 2. Hydrosilylation Using Homogeneous Catalysts.- 3. Catalytic Asymmetric Hydrosilylation of Prochiral Olefins.- 4. Selective Reduction of Carbonyl Compound via Hydrosilylation Catalyzed by a Rhodium(I) Complex.- 5. Asymmetric Reduction of Ketones via Catalytic Hydrosilylation.- 6. Asymmetric Reduction ofCarbon-Nitrogen Double Bond via Hydro-silylation.- 7. Asymmetric Synthesis of Bifunctional Organosilicon Compounds via Hydrosilylation.- 8. Conclusion.- 9. Acknowledgments.- 10. Abbreviations for Ligand Names.- 11. References.

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