|
|
|||
|
||||
OverviewThe catalytic vinylation reaction of 3,5-dimethylheptadiin-1,6-diol-3,5, 2,5-diphenylhexin-3-diol-2,5, 3,6-dimethyloctyne-4-diol-3,6, 1,3-dihydroxybenzene, butyne-2-diol-1,4 in the presence of acetylene by homogeneous and heterogeneous catalytic methods at atmospheric and high pressure and it was found that the corresponding mono- and divinyl derivatives of diols were formed. The nature and amount of catalyst, nature of solvent, temperature, molar ratio of acetylene and diol, acetylene feed rate and optimum conditions for the process were determined. The kinetics of the process of vinylation of diols with acetylene was studied and the value of activation energy for each process was calculated. Quantum-chemical calculations of selected diols and vinyl compounds synthesized on their basis were carried out, mathematical processing of experimental results was carried out and mathematical modeling of the vinylation process was carried out. On the basis of the obtained results and presented regularities the mechanism of formation of mono- and divinyl compounds of diols was proposed. The biological activity of the synthesized compounds was studied. Full Product DetailsAuthor: Lola JusupovaPublisher: Our Knowledge Publishing Imprint: Our Knowledge Publishing Dimensions: Width: 15.20cm , Height: 1.40cm , Length: 22.90cm Weight: 0.363kg ISBN: 9786206970545ISBN 10: 620697054 Pages: 244 Publication Date: 29 December 2023 Audience: General/trade , General Format: Paperback Publisher's Status: Active Availability: In Print This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us. Table of ContentsReviewsAuthor InformationTab Content 6Author Website:Countries AvailableAll regions |