Overview

The major emphasis here is on enantioselective reactions using asymmetric catalysts. Examples from the total synthesis of various natural and unnatural targets validates the utility of the synthetic methods. Specific topics discussed: cycloaddition, cycloisomerization and sigmatropic rearrangement reactions, allylic and carbonyl functionalization reactions, metal-catalyzed cross-coupling reactions, desymmetrization, fluorination, polymerization and sulfide oxidation reactions. This volume is part of a 3-volume set: Science of Synthesis Stereoselective Synthesis Workbench Edition Further information about Stereoselective Synthesis (including sample pages and the table of contents)

Full Product Details

Author:   P. Andrew Evans ,  Corinne Aubert ,  Jean-Francois Carpentier ,  Matthew Crawley
Publisher:   Thieme Publishing Group
Imprint:   Thieme Publishing Group
Edition:   1. Auflage
Volume:   2010/9
Weight:   0.454kg
ISBN:  

9783131541314

ISBN 10:   3131541318
Pages:   1166
Publication Date:   20 April 2011
Audience:   College/higher education ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   Out of stock  
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Table of Contents

3.1 [m+n]-Cycloaddition Reactions (Excluding [4+2]) 3.2 [4+2]-Cycloaddition Reactions 3.3 [m+n+1]-Carbocyclization Reactions 3.4 [m+n+2]-Carbocyclization Reactions 3.5 Asymmetric Cycloisomerizations 3.6 Ene Reactions 3.7 Sigmatropic Rearrangements 3.8 Electrocyclic Reactions 3.9 Allylic Substitution Reactions 3.10 Isomerizations To Form a Stereogenic Center and Allylic Rearrangements 3.11 Allylic and Benzylic Oxidation 3.12 Mizoroki–Heck Reaction 3.13 C—C Bond Formation by C—H Bond Activation 3.14 Cross Coupling 3.15 Protonation, Alkylation, Arylation, and Vinylation of Enolates 3.16 α-Functionalization of Carbonyl Compounds 3.17 Baeyer–Villiger Reactions 3.18 Ring Opening of Epoxides, Aziridines, and Cyclic Anhydrides 3.19 Acylation of Alcohols and Amines 3.20 Asymmetric Fluorination, Monofluoromethylation, Difluoromethylation, and Trifluoromethylation Reactions 3.21 Stereoselective Polymerization 3.22 Oxidation of Sulfides

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