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Author:   Xiao Shen (Wuhan University, China) ,  Yunxiao Zhang (Wuhan University, China) ,  Gang Zhou (Wuhan University, China)
Publisher:   Wiley-VCH Verlag GmbH
Imprint:   Blackwell Verlag GmbH
ISBN:  

9783527354634

ISBN 10:   3527354638
Pages:   336
Publication Date:   18 February 2026
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Awaiting stock  
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Table of Contents

1. Introduction 2. Generation of a-siloxy radicals with a-silyl alcohols through radical Brook rearrangement 2.1 Radical initiated reactions 2.2 Metal-catalyzed reactions 2.3 Photocatalyzed reactions 2.4 Other reactions 3. Generation of a-siloxy radicals with acylsilanes through radical Brook rearrangement 3.1 Radical initiated reactions 3.2 Metal-catalyzed reactions 3.3 Photocatalyzed reactions 4. Generation of a-siloxy silyl radicals with (TMS)3SiOH through radical Brook rearrangement 4.1 Metallaphotoredox reactions 4.2 Photoredox reactions 4.3 Metallaphotoredox reactions with (TMS)3SiNHAd 5. Generation of siloxycarbenes for nucleophilic addition reaction 5.1 Aldehydes or ketones as electrophiles 5.2 Other electrophilic reagents 6. Generation of siloxycarbenes for insertion reactions 6.1 Carbene insertion reactions into O?H bonds 6.2 Carbene insertion reactions into N?H bonds 6.3 Carbene insertion reactions into other X?H bonds 6.4 Carbene insertion reactions into B?C bonds 6.5 Carbene insertion reactions into C?H bonds 7. Generation of siloxycarbenes for cycloaddition reactions 7.1 [2+1] cycloaddition with alkyne 7.2 [2+1] cycloaddition with alkene 7.3 [4+1] cycloaddition with diene 7.4 Other cyclization reactions 8. Generation of siloxycarbenes for metal siloxycarbene reactions 9. Generation of silenes through radical Brook rearrangement 9.1 Insertion reactions 9.2 Cycloaddition reactions 9.3 Other reactions

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Author Information

Xiao Shen is Professor at the Institute for Advanced Studies, Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, State Key Laboratory of Metabolism and Regulation in Complex Organisms, Wuhan University, China. He is the winner of 2025 RSC Fluorine Prize. He serves on the Advisory Board of Chem Catalysis, the Early-Career Advisory Board of Organic Chemistry Frontiers, and is an Early-Career Editorial Board Member for Chinese Chemical Letters and the Chinese Journal of Organic Chemistry. Yunxiao Zhang is a postdoctoral fellow of The Institute for Advanced Studies at Wuhan University, China. Gang Zhou is a postdoctoral fellow of The Institute for Advanced Studies at Wuhan University, China.

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