|
![]() |
|||
|
||||
OverviewOrganoselenium chemistry is proving increasingly valuable to the synthetic organic chemist. Selenium residues are easily introduced into organic molecules, they serve to effect a variety of useful transformations, and are easily removed at the end of the sequence. These processes are often characterized by high chemo- regio- and stereoselectivity. Recent enantioselective variations of selenium-mediated reactions are further extending their scope and utility. The use of organoselenium compounds in organic conductors is another area of intense current interest. Organoselenium Chemistry - A Practical Approach is written by an international group of experts in the field. Full Product DetailsAuthor: Thomas G. Back (Department of Chemistry, University of Calgary)Publisher: Oxford University Press Imprint: Oxford University Press Dimensions: Width: 16.00cm , Height: 2.10cm , Length: 24.10cm Weight: 0.569kg ISBN: 9780198501411ISBN 10: 0198501412 Pages: 310 Publication Date: 22 July 1999 Audience: Professional and scholarly , Professional & Vocational Format: Hardback Publisher's Status: Out of Print Availability: In Print ![]() Limited stock is available. It will be ordered for you and shipped pending supplier's limited stock. Table of ContentsPreface 1: Back: Organoselenium chemistry: an overview 2: Back: Selenoxide eliminations 3: Beaulieu and Deziel: Addition of Electrophilic Organoselenium Reagents to Carbon-Carbon Double Bonds 4: Engman & Gupta: Reactions of selenium nucleophiles 5: Back: Oxidations with selenium reagents 6: Nishiyama & Sonoda: Reductions with selenium reagents 7: Chieffi & Comasseto: Reactions of selenium-stabilized carbanions 8: Hermans & Hevesi: Reactions of selenium stabilized carbocations 9: Back: Free-radical reactions and reductive deselenizations 10: Guziec Jr & Guziec: Selenium extrusion reactions 11: Nishibayashi & Uemura: Sigmatropic rearrangements of organoselenium compounds 12: Fujiwara, Kambe & Sonoda: Synthesis and reactions of carbonyl selenide and isoselenocyanates 13: Toshimisu & Uemura: Reactions of selenones 14: Ogura & Takimiya: Preparation of organic conductors Bibliography Appendix IndexReviewsSelenium is proving increasing [sic] valuable to synthetic organic chemists because residues of it are easily introduced into organic molecules, serve to effect a variety of useful transformations, and are easily removed at the end of the sequence, not unlike the best of lovers. Chemists who have specialized in its use survey the literature, emphasizing the most useful techniques and reagents. They offer detailed procedures for preparing key organoselenium reagents and for carrying out diverse types of reactions with them. A sampling of topics turns up adding electrophilic organoselenium reagents to carbon-carbon double bonds, oxidations with selenium reagents, reactions of selenium-stabilized carbocations, the synthesis and reactions of carbonyl selenide and isoselenocyanates, and preparing organic conductors. The treatment should be useful for organic chemists with or without previous experience using selenium. --SciTech Book News<br> Selenium is proving increasing [sic] valuable to synthetic organic chemists because residues of it are easily introduced into organic molecules, serve to effect a variety of useful transformations, and are easily removed at the end of the sequence, not unlike the best of lovers. Chemists who have specialized in its use survey the literature, emphasizing the most useful techniques and reagents. They offer detailed procedures for preparing key organoselenium reagents and for carrying out diverse types of reactions with them. A sampling of topics turns up adding electrophilic organoselenium reagents to carbon-carbon double bonds, oxidations with selenium reagents, reactions of selenium-stabilized carbocations, the synthesis and reactions of carbonyl selenide and isoselenocyanates, and preparing organic conductors. The treatment should be useful for organic chemists with or without previous experience using selenium. --SciTech Book News Author InformationProfessor Thomas G. Back Department of Chemistry University of Calgary 2500 University Drive N. W. Calgary, AB, Canada, T2N 1N4 Tab Content 6Author Website:Countries AvailableAll regions |