Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions
Author:   Robert A. Sánchez-Delgado
Publisher:   Springer-Verlag New York Inc.
Edition:   2002 ed.
Volume:   24
ISBN:  

9781402005350


Pages:   212
Publication Date:   30 April 2002
Format:   Hardback
Availability:   Awaiting stock   Availability explained
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Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions


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Overview

The hydrodesulfurization and hydrodenitrogenation of petroleum and refinery cuts have been in continuous development and in industrial practice for several decades. Environmental constraints regarding the quality of fuels has produced a renaissance of this field as the search for novel solution to this problem intensifies. This volume reviews the structures, bonding and reactions of metal complexes of the thiophenes and other HDS-related molecules, as well as of some HDN-related organinitrogen compounds. This chemistry is analyzed in the context of modelling some key species and reactions implicated in HDS and HDN catalysis. Many parallels are drawn between organometallic and surface chemistry, and homogeneous and heterogeneous catalysis. The book should be of value to chemistry and chemical engineers in academic and industrial environments, since the organometallic modeling approach emerges as a powerful tool to aid in the understanding of the structures and reaction mechanisms occurring in real systems, and in the design of novel HDS and HDN catalysts.

Full Product Details

Author:   Robert A. Sánchez-Delgado
Publisher:   Springer-Verlag New York Inc.
Imprint:   Springer-Verlag New York Inc.
Edition:   2002 ed.
Volume:   24
Weight:   0.494kg
ISBN:  

9781402005350


ISBN 10:   1402005350
Pages:   212
Publication Date:   30 April 2002
Audience:   College/higher education ,  Professional and scholarly ,  Undergraduate ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   Awaiting stock   Availability explained
The supplier is currently out of stock of this item. It will be ordered for you and placed on backorder. Once it does come back in stock, we will ship it out for you.

Table of Contents

Hydrodesulfurization and Hydrodenitrogenation.- Coordination and Activation of Thiophenes in Metal Complexes.- Hydrogenation Reactions.- Ring Opening, Hydrogenolysis and Desulfurization of Thiophenes by Metal Complexes.- Activation of Hydrogen on Metal Complexes with Sulfide Ligands and Related Coordination Chemistry of H2S.- Modeling Hydrodenitrogenation.

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