Overview

Organometallic Ion Chemistry features eight chapters, written by acknowledged authorities, covering the gas-phase chemistry of organometallic ions. Topics covered include: periodic trends in gas-phase thermochemistry of transition metal-ligand systems; ab initio calculations to determine electronic structure, geometric structure, and thermochemistry of metal-containing systems; electronic state effects on metal ion reactivity; organometallic ion photochemistry; applications of gas-phase electron transfer equilibria in organometallic redox thermochemistry. Also included are state of the art mass spectrometric instrumentation used in such studies. Finally, the book features - for the first time in one place - a comprehensive list (containing over 1500 entries) of metal ion-ligand bond energies, obtained from theory and experiment. An invaluable reference source for ion chemists, organometallic chemists and surface chemists, at both expert and graduate student levels.

Full Product Details

Author:   B.S. Freiser
Publisher:   Springer
Imprint:   Springer
Edition:   Softcover reprint of the original 1st ed. 1996
Volume:   15
Dimensions:   Width: 15.50cm , Height: 1.90cm , Length: 23.50cm
Weight:   0.539kg
ISBN:  

9789401065368

ISBN 10:   9401065365
Pages:   337
Publication Date:   23 August 2014
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   Manufactured on demand  
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Table of Contents

1. Gas-Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends.- 2. Ab Initio Calculations Applied to Problems in Metal Ion Chemistry.- 3. The Electronic Structure of the Neutral, Mono and Di Positive Transition Metal Nitrides, ScN, TiN, VN and CrN.- 4. Fundamental Studies of Functionalized Hydrocarbons with Transition-Metal Ions.- 5. Electronic State Effects in Sigma Bond Activation by First Row Transition Metal Ions: The Ion Chromatography Technique.- 6. Development of a Fourier-Transform Ion Cyclotron Resonance (FTICR) Mass Spectrometry Method for Studies of Metal Ion Excited States.- 7. Gas-Phase Organometallic Ion Photochemistry.- 8. Applications of Gas-Phase Electron-Transfer Equilibria in Organometallic Redox Thermochemistry.- Table of Bond Energies.

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