Overview

Organolithium chemistry occupies a central position in the selective construction of C-C bonds in both simple and complex molecules. Paralleling the surge of interest in methods for asymmetric synthesis, the use of organolithiums in enantioselective synthesis has witnessed spectacular advances in a little over a decade. This volume is the first dedicated to a comprehensive coverage of this important area. It is designed to provide graduate students and researchers with a rich source of essential information on synthesising molecules in an enantioselective manner using organolithiums, and be an inspiration for future developments. Following an overview chapter summarising the key milestones, successive chapters, each written by leading experts in their field, critically survey all the major areas of progress.

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This book is a valuable addition to the Topics in Organo-metallic Chemistry series that has successfully culled a vast topic into engaging and focused chapters through skillful editorship. With minimal redundancy, the short text provides comprehensive coverage of stereoselective deprotonations using alkyllithiums in the presence of sparteine; the presentation balances uninspiring examples with those in which the effectiveness of the asymmetric depronation strategy is unsur-passed. Interspersed throughout are complementary methods for the creation and utilization of organolithiums in myriad reactions that contribute meaningfully to the usefulness of the text. Clear chapter headings and subject/author indexes make finding information easy, and the volume will be a useful addition to library reference collections. Brian L. Pagenkopf, University of Texas at Austin J. Am. Chem. Soc. 2003 To cover this very large subject, which has grown in size over several decades and continues to develop rapidly, in such a compact form, as in this volume, was certainly a demanding task, but it has been done successfully. Through the sensible choice of topic areas and by the arrangement of the material under different headings, the reader is given easy access to this complex subject. Bernd Goldfuss Institut fur Organische Chemie Universitat Koln Angewandte Chemie Int. Ed. 2004, 43, 778-781 www.angewandte.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim ------ In this monograph, which is the newest addition to the excellent Topics in Organometallic Chemistry series, several authors from eight research groups around the world describe the current state of the art in the area of stereoselectivity control using organolithium reagents. This book is a fine addition to any collection of synthetic monographs or to a library centering on organometallic reactions. Practitioners of stereoselective synthesis of natural products will likely find it very useful. Marek Majewski University of Saskatchewan, Canada Adv. Synth. Catal. 2005, 347, 719-720 Wiley-VCH

This book is a valuable addition to the Topics in Organo-metallicChemistry series that has successfully culled a vasttopic into engaging and focused chapters through skillfuleditorship. With minimal redundancy, the short text providescomprehensive coverage of stereoselective deprotonations usingalkyllithiums in the presence of sparteine; the presentationbalances uninspiring examples with those in which the effectivenessof the asymmetric depronation strategy is unsur-passed. Interspersed throughout are complementary methods forthe creation and utilization of organolithiums in myriad reactionsthat contribute meaningfully to the usefulness of the text. Clearchapter headings and subject/author indexes make findinginformation easy, and the volume will be a useful addition tolibrary reference collections.Brian L. Pagenkopf, University of Texas at Austin J. Am. Chem. Soc. 2003 To cover this very large subject, which has grown in size over severaldecades and continues to develop rapidly, in such a compact form, as in thisvolume, was certainly a demanding task, but it has been done successfully.Through the sensible choice of topic areas and by the arrangement of thematerial under different headings, the reader is given easy access to this complex subject. Bernd GoldfussInstitut fur Organische ChemieUniversitat Koln Angewandte Chemie Int. Ed. 2004, 43, 778-781www.angewandte.org2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim ------ In this monograph, which is the newest addition to the excellent Topics in Organometallic Chemistry series, several authors from eight research groups around the world describe the current state of the art in the area of stereoselectivity control using organolithium reagents.This book is a fine addition to any collection of synthetic monographs or to a library centering on organometallic reactions. Practitioners of stereoselective synthesis of natural products will likely find it very useful. Marek MajewskiUniversity of Saskatchewan, Canada Adv. Synth. Catal. 2005, 347, 719-720Wiley-VCH

This book is a valuable addition to the Topics in Organo-metallic Chemistry series that has successfully culled a vast topic into engaging and focused chapters through skillful editorship. With minimal redundancy, the short text provides comprehensive coverage of stereoselective deprotonations using alkyllithiums in the presence of sparteine; the presentation balances uninspiring examples with those in which the effectiveness of the asymmetric depronation strategy is unsur-passed. Interspersed throughout are complementary methods for the creation and utilization of organolithiums in myriad reactions that contribute meaningfully to the usefulness of the text. Clear chapter headings and subject/author indexes make finding information easy, and the volume will be a useful addition to library reference collections. Brian L. Pagenkopf, University of Texas at Austin J. Am. Chem. Soc. 2003 To cover this very large subject, which has grown in size over several decades and continues to develop rapidly, in such a compact form, as in this volume, was certainly a demanding task, but it has been done successfully. Through the sensible choice of topic areas and by the arrangement of the material under different headings, the reader is given easy access to this complex subject. Bernd Goldfuss Institut für Organische Chemie Universität Köln Angewandte Chemie Int. Ed. 2004, 43, 778-781 www.angewandte.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim ------ In this monograph, which is the newest addition to the excellent Topics in Organometallic Chemistry series, several authors from eight research groups around the world describe the current state of the art in the area of stereoselectivity control using organolithium reagents. This book is a fine addition to any collection of synthetic monographs or to a library centering on organometallicreactions. Practitioners of stereoselective synthesis of natural products will likely find it very useful. Marek Majewski University of Saskatchewan, Canada Adv. Synth. Catal. 2005, 347, 719-720 Wiley-VCH

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