Overview

This volume contains a description of the synthesis, structure, physicochemical and catalytic properties of organometallic complexes of yttrium, scandium, lanthanum and lanthanoids. Along with the true organometallics, the alcoholates, thiolates, amides and similar classes of compounds are considered. The last section of the book deals with practical applications of organic derivatives of rare earth elements. The book contains a large number of tables and illustrations giving physicochemical, spectral and structural characteristics or organoderivatives of lanthanoids. The comprehensive data presented obviate the need to refer to original publications.

Full Product Details

Author:   M.N. Bochkarev ,  Lev N. Zakharov ,  Galina S. Kalinina
Publisher:   Springer
Imprint:   Springer
Edition:   1995 ed.
Volume:   3
Dimensions:   Width: 15.50cm , Height: 3.00cm , Length: 23.50cm
Weight:   2.060kg
ISBN:  

9780792331537

ISBN 10:   0792331532
Pages:   533
Publication Date:   31 July 1995
Audience:   College/higher education ,  Professional and scholarly ,  Undergraduate ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

I. ?-Alkyl and ?-aryl complexes.- I.1. Di-and trialkyl(aryl)lanthanoids.- 1.2. Complexes of ate-type.- I.3. Compounds with cyclopentadienyl and ?1-bonded ligands.- I.4. Compounds with cyclooctatetraenyl and ?1-bonded ligands.- I.5. Ylide and zwitterionic complexes.- References.- II ?3-Allyl and similar complexes.- II.1. Synthesis and properties.- 11.2. Spectroscopic data.- References.- III Cyclopentadienyl derivatives.- III.1. Dicyclopentadienyl complexes.- I11.2. Tricyclopentadienyl complexes.- III.3. Complexes with coordinate bonded ligands.- 111.4. Halides and related compounds of REM cyclopentadienides.- III.5. Heterobimetallic complexes of ate-type.- References.- IV Complexes with the cyclic polyene ligands.- IV.1. Indenyl complexes.- IV.2. Fluorenyl complexes.- IV.3. Cycloheptatrienyl complexes.- IV.4. Cyclooctatetraenyl complexes.- IV. 5. Arene complexes of lanthanoids.- References.- V Organohydrides of lanthanoids.- V.1. Synthesis.- V.2. Structure.- V.3. Properties.- V.4. Spectral data.- References.- VI Compounds with a Ln-N bond.- VI.1. Synthesis.- VI.2. Structure.- VI.3. Properties.- References.- VII Compounds with Ln-P and Ln-As bonds.- VII.1. Phosphorus derivatives.- VII.2. Arsenic derivatives.- References.- VIII Compounds with a Ln-O bond.- VIII. 1. Alkoxides of Ln(OR)3 type.- VIII.2. Halide/alkoxides of REM and other derivatives of the Ln(OR)3-xYxtype.- VIII.3. Alkoxides, oxides and hydroxides of cyclopentadienyllanthanoids.- VIII.4. Bimetallic alkoxides.- References.- IX The compounds with a lanthanoid-chalcogen bond.- IX.1. Synthesis and properties.- IX.2. Structure.- References.- X Compounds with lanthanoid-metal bonds.- X.1. The derivatives of nontransition metals.- X.2. Complexes of REM with carbonyls and nitrosyls oftransition metals.-References.- XIComplexes of Ce(IV).- References.- XII Miscellaneous compounds.- XII.1. Carbonyls.- XII.2. Graphite intercalates.- XII.3. Phthalocyanines and porphyrins.- XII.4. Complexes with other nitrogen containing ligands.- XII.5. Products of gas phase reactions of Ln+ with hydrocarbons.- XII.6. Clusters.- References.- XIII Applications of organolanthanoids.- XIII.1. Catalysis of polymerization.- XIII.2. Catalysts and reagents for reductionand oxidation processes.- XIII.3. Miscellaneous applications of REM compounds.- References.

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