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OverviewMost organic chemical reactions are carried out in an organic solvent, with no thought being given to whether it is necessary to do so, with the associated problems of reaction efficiency and potential pollution problems. It was discovered recently that most organic reactions can be conducted in the absence of solvent in the solid state. In many cases, the solid state reaction proceeds more easily and efficiently, with even greater selectivity than in solution, showing that molecules move easily and selectively in the solid state. There are many avenues to explore in studying organic solid state reactions, such as enantioselective reactions, which can easily be performed in an inclusion complex crystal with an optically active host. Catalytic reactions in the solid state are often more economically and ecologically profitable than the liquid state counterparts. The six contributions collected here present a guide to the possibilities and opportunities afforded by solid state organic reactions. Full Product DetailsAuthor: Fumio TodaPublisher: Springer-Verlag New York Inc. Imprint: Springer-Verlag New York Inc. Edition: 2002 ed. Dimensions: Width: 15.50cm , Height: 1.70cm , Length: 23.50cm Weight: 1.300kg ISBN: 9781402002274ISBN 10: 1402002270 Pages: 275 Publication Date: 30 April 2002 Audience: College/higher education , Professional and scholarly , Undergraduate , Postgraduate, Research & Scholarly Format: Hardback Publisher's Status: Active Availability: In Print ![]() This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us. Table of Contents1. Thermal Organic Reaction in the Solid State; K. Tanaka, F. Toda. 2. Intermolecular Methyl Migration in the Solid-State; M. Kaftory. 3. Solid-State Ionic Reactions; K. Kobayashi. 4. Organic Photoreaction in the Solid State; K. Tanaka, F. Toda. 5. Achieving Enantio and Diastereoselectivities in Photoreactions through the Use of a Confined Space; J. Sivaguru, J. Shailaja, S. Uppili, K. Ponchot, A. Joy, N. Arunkumar, V. Ramamurthy. 6. Solid State Bimolecular Photoreactions in Two-Component Molecular Crystals; H. Koshima.ReviewsAuthor InformationTab Content 6Author Website:Countries AvailableAll regions |