Orbital Symmetry and Reaction Mechanism: The OCAMS View

Author:   E.Amitai Halevi
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Edition:   Softcover reprint of the original 1st ed. 1992
ISBN:  

9783642835704


Pages:   312
Publication Date:   20 September 2012
Format:   Paperback
Availability:   Manufactured on demand   Availability explained
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Orbital Symmetry and Reaction Mechanism: The OCAMS View


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Overview

Criteria of orbital symmetry conservation had a profound influence on mechanistic thinking in organic chemistry and are still commonly applied today. The author presents a coherent set of operational rules for the analysis of scope and reliability. It is written from the viewpoint of Orbital Correspondence Analysis in Maximum Symmetry (OCAMS). Its advantage lies in its provision of a coherent overview of the relation between symmetry and mechanism. For reasons of consistency, the book remains within the framework of molecular orbital theory.

Full Product Details

Author:   E.Amitai Halevi
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   Softcover reprint of the original 1st ed. 1992
Dimensions:   Width: 15.50cm , Height: 1.80cm , Length: 23.50cm
Weight:   0.522kg
ISBN:  

9783642835704


ISBN 10:   3642835708
Pages:   312
Publication Date:   20 September 2012
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   Manufactured on demand   Availability explained
We will order this item for you from a manufactured on demand supplier.

Table of Contents

I. Preliminary Survey.- 1. The Woodward-Hoffmann Rules in Perspective.- II. Symmetry and Energy.- 2. Atoms and Atomic Orbitals.- 3. Diatomic Molecules and Their Molecular Orbitals.- 4. Formation and Deformation of Polyatomic Molecules.- III. The Classical Thermal Reactions.- 5. Electrocyclic Reactions and Related Rearrangements.- 6. Cycloadditions and Cycloreversions: I. [2+2]-Cycloaddition.- 7. Cycloadditions and Cycloreversions: II. Beyond [2+2].- 8. Degenerate Rearrangements.- IV. Spin and Photochemistry.- 9. Electron Spin.- 10. Excited State Reactions.- 11. Into Inorganic Chemistry.- A. Character Tables of the More Common Symmetry Point Groups.- B. Kernels and Co-Kernels of Degenerate Irreducible Representations.- C. Group Correlation Tables.

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