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Author:   R.N. Ibbett
Publisher:   Chapman and Hall
Imprint:   Chapman and Hall
Edition:   1993 ed.
Dimensions:   Width: 15.50cm , Height: 2.30cm , Length: 23.50cm
Weight:   1.580kg
ISBN:  

9780751400052

ISBN 10:   075140005
Pages:   362
Publication Date:   30 September 1993
Audience:   College/higher education ,  Professional and scholarly ,  Undergraduate ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

1 Introduction to NMR and its use in the study of polymer stereochemistry.- 1.1 Introduction.- 1.2 Basic principles of NMR.- 1.3 The form of a liquid-state NMR spectrum.- 1.4 Nuclear magnetic relaxation.- 1.5 Experimental practice in high-resolution solution-state NMR of polymers.- 1.6 Advanced Fourier transform techniques.- 1.7 A survey of applications of high-resolution solution-state NMR to polymers.- 1.8 The observation of polymer stereochemistry (tacticity) by NMR.- 1.9 Summary.- References.- 2 Statistical analysis of copolymer sequence distribution.- 2.1 Introduction.- 2.2 Copolymerisation statistics and models.- 2.3 Examples of the use of copolymer statistics.- 2.4 In situ methods and simulation techniques.- 2.5 Polymer modification.- 2.6 Summary.- References.- 3 Solution-state NMR determination of polymer end-groups, substituents and minor structures.- 3.1 Introduction.- 3.2 End-groups.- 3.3 In-chain units.- 3.4 Branching.- 3.5 Chemical modification of polymers.- 3.6 Concluding comments.- References.- 4. Liquid state NMR studies of polymer dynamics and conformation.- 4.1 Introduction.- 4.2 NMR relaxation theory.- 4.3 The dynamics of flexible molecules and macromolecules.- 4.4 The conformational states of polymers.- 4.5 Application of conformational theory to relaxation and NOE.- 4.6 Experimental methods.- References.- 5 High-resolution solid-state NMR studies of polymer chemical and physical structures.- 5.1 Introduction.- 5.2 High-resolution NMR spectroscopy of solids.- 5.3 Acquisition and analyses of solid-state 13C NMR spectra.- 5.4 Applications of high-resolution CPMAS/DD NMR to polymer solids.- 5.5 Summary.- References.- 6 High-resolution solid-state 13C NMR studies of local motions and spin dynamics in bulk polymers.- 6.1 Introduction.- 6.2 13C NMR investigation of local dynamics in bulk polymers at temperatures well above the glass-transition temperature.- 6.3 13C NMR investigation of local dynamics in bulk polymers at temperatures below the glass-transition temperature.- 6.4 13C NMR study of the molecular organization of some solid heterogeneous polymer systems.- 6.5 Conclusion.- References.- 7 Solid-state proton NMR studies of polymers.- 7.1 Introduction.- 7.2 Heterogeneity in solid polymers.- 7.3 Underlying theory: the dipolar interaction.- 7.4 Experimental methods.- 7.5 Lineshape/FID analysis of polymers.- 7.6 Relaxation time analysis of polymers.- 7.7 Spin diffusion in relaxation methods for polymers.- 7.8 Attempts to observe spin diffusion directly.- 7.9 Attempts to suppress spin diffusion in relaxation measurements.- 7.10 High-resolution proton methods for polymers, MAS and CRAMPS.- 7.11 Carbon detection of proton magnetisation.- 7.12 Oriented polymers.- 7.13 Conclusions.- References.- 8 Deuterium NMR of synthetic polymers.- 8.1 Introduction.- 8.2 Experimental theory.- 8.3 Polymer orientation.- 8.4 Polymer motion.- 8.5 Multi-dimensional experiments.- 8.6 Conclusions.- Acknowledgements.- References.- 9 NMR in polymers using magnetic field gradients: imaging, diffusion and flow.- 9.1 Introduction.- 9.2 Theory.- 9.3 Applications of NMR imaging in polymers.- 9.4 Pulsed gradient spin echo diffusion studies in polymers.- 9.5 Flow studies using dynamic NMR imaging.- 9.6 q-Space imaging of morphology in colloidal and polymeric systems.- 9.7 Conclusions.- References.

Reviews

Its chapters form a coherent whole that covers the area of the title comprehensively and neatly...nicely produced, with good-quality diagrams, and it is amply referenced for further reading...There is also a substantial index. Altogether I believe this book is to be highly recommended to all polymer chemists interested in NMR and to all NMR spectroscopists involved with polymers - Trends in Polymer Science

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