Overview

Provides a comprehensive overview of N[2O[5 chemistry. Reports electrochemical synthesis of N[2O[5 in nitric acid and isolation of aproptic N[2O[5. Discusses scaling up the synthesis of N[2O[5 in both the laboratory and bulk processes. Presents synthesis of new explosives and propellant ingredients, including cage and heterocyclic compounds and new energetic polymers. Reports non-acidic nitration of compounds using N[2O[5.

Full Product Details

Author:   Lyle F. Albright ,  Richard V.C. Carr ,  Robert J. Schmitt
Publisher:   American Chemical Society
Imprint:   American Chemical Society
Volume:   623
Dimensions:   Width: 15.60cm , Height: 2.40cm , Length: 23.40cm
Weight:   0.521kg
ISBN:  

9780841233935

ISBN 10:   0841233934
Pages:   296
Publication Date:   01 January 1996
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   No Longer Our Product
Availability:   In Print  
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Table of Contents

Nitration: An Overview of Recent Developments and Processes ; Role of Protosolvation in Nitrations with Superacidic Systems: The Protonitronium Dication (NO[2H^2]+) Identified ; Nitrocyclohexadienones in Aromatic Nitration ; Aromatic Nitration in Liquid Nitrogen Tetroxide Promoted by Metal Acetylacetonates ; Synthesis of 2,5,7,9-Tetranitro-2,5,7,9-tetraazabicyclo[4.3.0]nonanone ; Photochemical Chlorocarbonylation: Simple Synthesis of Polynitroadamantanes and Polynitrocubanes ; Isolation of Electrochemically Generated Dinitrogen Pentoxide in a Pure Form and Its Use in Aromatic Nitrations ; Pilot-Plant Scale Continuous Manufacturing of Solid Dinitrogen Pentoxide ; Separation of Dinitrogen Pentoxide from Its Solutions in Nitric Acid ; Nitrated Hydroxy-Terminated Polybutadiene: Synthesis and Properties ; Novel Syntheses of Energetic Materials Using Dinitrogen Pentoxide ; A New Route to Nitramines in Nonacidic Meda ; Reinvestigation of the Ponzio Reaction for the Preparation of gem-Dinitro Compounds ; New Nitration and Nitrolysis Procedures in the Synthesis of Energetic Materials ; Flow Reactor Nitrations Using Dinitrogen Pentoxide ; Modeling to Gain Insight into Thermal Decomposition of Dinitrotoluene ; Removal and Destruction of Tetranitromethane from Nitric Acid ; Modeling Nitronium Ion Concentrations in HNO[3-H[2SO[4-H[2O Mixtures ; Commercial Dinitrotoluene Production Process ; Recent Advances in the Technology of Mononitrobenzene Manufacture ; Industrial Nitration of Toluene to Dinitrotoluene: Requirements of a Modern Facility for the Production of Dinitrotoluene ; Practical Considerations in Concentration and Recovery of Nitration-Spent Acids

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