Late Transition Metal-Carboryne Complexes: Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes
Author:   Zaozao Qiu
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Edition:   2012
ISBN:  

9783642243608


Pages:   134
Publication Date:   05 January 2012
Format:   Hardback
Availability:   Awaiting stock   Availability explained
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Late Transition Metal-Carboryne Complexes: Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes


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Overview

Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.

Full Product Details

Author:   Zaozao Qiu
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   2012
Dimensions:   Width: 15.50cm , Height: 1.00cm , Length: 23.50cm
Weight:   0.401kg
ISBN:  

9783642243608


ISBN 10:   3642243606
Pages:   134
Publication Date:   05 January 2012
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Awaiting stock   Availability explained
The supplier is currently out of stock of this item. It will be ordered for you and placed on backorder. Once it does come back in stock, we will ship it out for you.

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