Iron-Carbene Complexes
Author:   Wolfgang Petz ,  J. Faust ,  J. Füssel
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Volume:   1
ISBN:  

9783540562580


Pages:   202
Publication Date:   29 April 1993
Format:   Paperback
Availability:   Out of stock   Availability explained
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Iron-Carbene Complexes


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Overview

E.O. Fischer received the Nobel prize in 1973 for the investigations of complexes with a formal metal atom-carbon double bond. Among these, the iron-carbene species is readily available and has proved to be a versatile reagent in organic syntheses. It is rather simple to tune the electronic properties of this Fischer Carbene and to control reactivity and stereospecificity of the reagent in cyclopropanation reactions. This first volume of the series addresses graduate students in the fields of co-ordination compounds and organic synthesis. It covers the chemistry and structural aspects of iron-carbon compounds with an iron-carbon double bond. The first part deals with the carbene moiety, the second with vinylidene ligands.

Full Product Details

Author:   Wolfgang Petz ,  J. Faust ,  J. Füssel
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Volume:   1
Dimensions:   Width: 15.50cm , Height: 1.10cm , Length: 23.50cm
Weight:   0.330kg
ISBN:  

9783540562580


ISBN 10:   3540562583
Pages:   202
Publication Date:   29 April 1993
Audience:   College/higher education ,  Postgraduate, Research & Scholarly
Format:   Paperback
Publisher's Status:   Active
Availability:   Out of stock   Availability explained
The supplier is temporarily out of stock of this item. It will be ordered for you on backorder and shipped when it becomes available.

Table of Contents

1 Carbene Complexes with the 5LFe=C Moiety.- 1.1 Cationic Carbene Complexes with One Carbene Ligand Bonded to Fe.- 1.2 Neutral Carbene Complexes.- 1.3 Anionic Carbene Complexes.- 1.4 Carbene Compounds with Two Carbene Ligands.- 2 Vinylidene Complexes.- 2.1 Cationic Complexes of the Type [5L(2D-2D)Fe=C=CRR’]+ or [5L(2D)2Fe=C=CRR,]+.- 2.2 Cationic Complexes of the Type [5L(CO)(2D)Fe=C=CRR’]+.- 2.3 Cationic Complexes of the Type [5L(CO)2Fe=C=CRR’]+.- 2.4 Cationic Compounds of the Type [Cp(CO)(2D)FeC(2D’)=CRR’]X, [Cp(CO)Fe(?-2D-2D’)C=CRR’]X, and [Cp(CO)2FeC(2D)=CRR’]X.

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