Overview

Offers an up-to-date account of fundamental and applied research and points to future directions in inorganic fluorine chemistry. Reviews the major advances in fluorine-containing substituent groups. Provides a critical examination of coordination numbers greater than six among fluorides and oxofluorides. Discusses attempts to control chemical reactivity and stability through the use of more nucleophilic sources of fluoride or, conversely, more weakly coordinating anions. Features chapters on new fluorine-containing ligands in organometallic, transition metal, solid state, lanthanide and actinide chemistry.

Full Product Details

Author:   Joseph S. Thrasher ,  Steven H. Strauss
Publisher:   American Chemical Society
Imprint:   American Chemical Society
Volume:   555
Dimensions:   Width: 15.60cm , Height: 2.60cm , Length: 23.40cm
Weight:   0.729kg
ISBN:  

9780841228696

ISBN 10:   0841228698
Pages:   497
Publication Date:   01 January 1994
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   No Longer Our Product
Availability:   In Print  
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Table of Contents

Inorganic Fluorine Chemistry: Toward the 21st Century ; Thermodynamic Aspects of the Remarkable Oxidizing Capabilities of Fluorine-Lewis-Fluoroacid Mixtures ; Photochemical and Thermal Dissociation Synthesis of Krypton Difluoride ; Main-Group Fluorides with Coordination Numbers Greater than Six ; Heptacoordinated Main-Group Fluorides and Oxofluorides ; Monofluoroxenonium Hexafluorometalates XeF]+MF[6[- (M = As or Sb): A Course to Different Onium Cations ; Influence of Fluorine and Parahalogen Substituents on the Chemistry of Some Functional Groups ; Functionalization of Pentafluoro-*l]6-sulfanyl (SF[5) Olefins and Acetylenes ; Fluoro-Sulfur Anions: Transition States, Intermediates, and Reagents ; Quest for an Aromatic Silicon Species: An Unusual Geometry around Silicon in a 10-Si-5 Siliconate ; Reaction of SiH[4 with UF[6 and HF below 25 C: Fourier Transform IR Study ; Fluorinated Aldehydes and Their Polymers ; Synthesis and Chemistry of Perfluoro Macrocycles: Perfluoro Crown Ethers and Cryptands ; Alkali Metal Polyhydrogen Fluorides: Useful Halogen-Exchanges Media ; New and Revisited Transition Metal Chemistry of Fluoro-olefins and Fluorodienes ; Organometallic Chemistry of Fluorinated Isocyanides ; Synthetic, Structural and Reactivity Studies of Organocobalt(III) Compounds Containing Fluorinated Alkyl Ligands ; Perfluorovinyl and Perfluoroaryl Zinc and Cadmium Reagents: Preparation, Stability, and Reactivity ; Organic and Main-Group Chemistry of the 2,4,6-Tris(trifluoromethyl)phenyl Substituent: Kinetic Stabilization through Steric and Electronic Effects ; Reaction of Nonmetal Fluorides with Some Platinum Metal Complexes ; Large Polyfluorinated Anions Used To Generate Coordinative Unsaturation in Cations ; Stabilization of Unusual Cations by Very Weakly Basic Fluoro Anions ; Synthesis, Structure, and Reactivity of Highly Soluble Organotitanium Lewis Acids ; New Synthetic Routes to Cyclopentadienyluranium(IV) Fluorides: Redox and Atom-Abstraction Reactions ; Activation of Carbon-Fluorine Bonds by Oxidative Addition to Low-Valent Transition Metals ; Recent Developments in the Chemistry of Fluorinated Isopropoxides and Tertiary Butoxides ; (Fluoroaklyl)phosphine Coordination Chemistry

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