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Author:   R. Dickson
Publisher:   Springer
Imprint:   Kluwer Academic Publishers
Edition:   1985 ed.
Volume:   8
Dimensions:   Width: 21.00cm , Height: 1.70cm , Length: 29.70cm
Weight:   1.320kg
ISBN:  

9789027718808

ISBN 10:   9027718806
Pages:   278
Publication Date:   30 September 1985
Audience:   College/higher education ,  Professional and scholarly ,  Postgraduate, Research & Scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

Some General Comments on Transition Metal Catalysts.- 1.1. Catalysts and Catalyst Recovery.- 1.2. Supported Catalysts.- 1.3. Organic Feedstocks.- 1.4. Organic Reactions Catalysed by Rhodium and Iridium Compounds.- The Activation of C—H and C—C Bonds: Dehydrogenation, H/D Exchange and Isomerization Reactions.- 2.1. The Activation of C — H Bonds in Saturated Hydrocarbons.- 2.2. Dehydrogenation.- 2.3. H/D Exchange.- 2.4. Unsaturated Alcohol to Aldehyde Conversions.- 2.5. Double-bond Migration.- 2.6. Geometric cis ? trans Isomerization.- 2.7. Intermodular Disproportionation Reactions.- 2.8. Valence Isomerization; Ring-opening Reactions.- The Formation of C—H Bonds: Hydrogenation and Related Reactions.- 3.1. RhCl(PPh3)3 and HRh(PPh3) a.- 3.2. M(CO)XL2.- 3.3. HM(CO)(PPh3)3.- 3.4. Other Catalysts with Carbonyl and Related ?-Acid Ligands.- 3.5. Catalysts Derived from Alkene and Diene Complexes of RhI and IrI.- 3.6. Complexes of MIII as the Catalyst Source.- 3.7. Catalysts Derived from RhII, Rh24+.- 3.8. Reductions via H-transfer from Alcoholic Solvents.- 3.9. Supported Hydrogenation Catalysts.- 3.10. Asymmetric Homogeneous Hydrogenation with Chiral Rhodium Complexes as Catalysts.- 3.11. Hydrosilation Reactions.- Carbonylation and Hydroformylation Reactions.- 4.1. The Water—Gas Shift Reaction.- 4.2. The Hydrogenation of CO; Synthesis Gas Chemistry.- 4.3. The Catalytic Reduction of NO by CO.- 4.4. Carbonylation Reactions.- 4.5. Hydroformylation; the Formation of Aldehydes from Alkenes.- Oxidation Reactions.- 5.1. Direct Reaction with O2.- 5.2. Other Means of Forming C—O Bonds.- Functional Group Removal.- 6.1. Decarbonylation.- 6.2. Desulfonylation.- 6.3. Deoxygenation, including the Decomposition of Hydroperoxides.- Oligomerization, Polymerization and RelatedCondensation Reactions.- 7.1. Alkene Dimerization and Polymerization.- 7.2. Diene Oligomerization and Polymerization.- 7.3. Alkene—Diene Co-oligomerization.- 7.4. Oligomerization and Polymerization of Cyclic Alkenes and Polyenes, including Ring-opening Reactions.- 7.5. The Oligomerization, Polymerization and Addition Reactions of Alkynes.- 7.6. The Formation of Functionalized Oligomers and Polymers.- 7.7. Other Reactions Leading to the Formation of New C —X Bonds.- Appendix. Tabulation of Catalysts and their Applications.- References.

Reviews

...provides a very readable and useful review of the present state of knowledge on catalysis involving rhodium and iridium species. Literature up to 1982 is comprehensively covered and very clear mechanistic schemes are provided, while in addition a helpful tabulation of homogeneous catalysts and their applications is presented as an Appendix.' Platinum Metals Review (1986)

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