High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure
Author:   Carola S. Vogel
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Edition:   2012 ed.
ISBN:  

9783642272530


Pages:   132
Publication Date:   04 February 2012
Format:   Hardback
Availability:   Manufactured on demand   Availability explained
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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure


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Overview

Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

Full Product Details

Author:   Carola S. Vogel
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   2012 ed.
Dimensions:   Width: 15.50cm , Height: 1.50cm , Length: 23.50cm
Weight:   0.401kg
ISBN:  

9783642272530


ISBN 10:   3642272533
Pages:   132
Publication Date:   04 February 2012
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Manufactured on demand   Availability explained
We will order this item for you from a manufactured on demand supplier.

Table of Contents

-Chapter 1: Introduction to Tripodal N-Heterocyclic Carbene Iron Complexes.- Chapter 2: TIMENmes − An Iron Nitride Complex. -Chapter 3: TIMENtol/3,5xyl Unexpected Reactivity Resulting from Modifications of the Ligand Periphery. -Chapter 4: TIMEN3,5CF3 Hybrid System Capable of Cyclometallation and Nitride Insertion. -Chapter 5: PhB(tBuIm)3 Synthesis, Structure, and Reactivity of an Iron(V) Nitride. -Chapter 6: PhB(MesIm)3 Spin Crossover in a Four-Coordinate Iron(II) Complex.

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