Overview

Heteroligand molecular systems with extremely varied properties are widespread in inorganic, coordination, and organometallic chemistry, areas which are developing rapidly and have a wide range of practical applications. There is currently a great deal of interest in such systems and this book aims to summarize and analyze the wealth of data concerning the structure, isomerism, and isomerization of heteroligan systems which has been accumulated. The first two chapters provide an introduction to quantum chemistry and the applications of perturbation theory to chemical problems. This theoretical basis is then used in the remaining chapters where perturbation theory methods are used to describe a wide range of problems related to the mutual influences of ligands and relative isomer stabilities in typical heteroligand molecules and complexes of nontransition and transition metals.

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