Functionalization of Carborane via Carboryne Intermediates
Author:   Da Zhao
Publisher:   Springer Verlag, Singapore
Edition:   Softcover reprint of the original 1st ed. 2016
ISBN:  

9789811093890


Pages:   170
Publication Date:   07 June 2018
Format:   Paperback
Availability:   Manufactured on demand   Availability explained
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Functionalization of Carborane via Carboryne Intermediates


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Overview

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.  

Full Product Details

Author:   Da Zhao
Publisher:   Springer Verlag, Singapore
Imprint:   Springer Verlag, Singapore
Edition:   Softcover reprint of the original 1st ed. 2016
Weight:   3.276kg
ISBN:  

9789811093890


ISBN 10:   981109389
Pages:   170
Publication Date:   07 June 2018
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   Manufactured on demand   Availability explained
We will order this item for you from a manufactured on demand supplier.

Table of Contents

Introduction.- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines.- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction.- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition.- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes.- Ene Reaction of 1,3-Dehydro-ο-Carborane.- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling.- Conclusion.- Experimental Section.

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