Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products

Author:   J. W. Daly ,  D. Ferreira ,  S. J. Gould ,  E. Haslam
Publisher:   Springer Verlag GmbH
Volume:   v.41
ISBN:  

9783211816905


Pages:   384
Publication Date:   June 1982
Format:   Hardback
Availability:   Out of stock   Availability explained
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Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products


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Author:   J. W. Daly ,  D. Ferreira ,  S. J. Gould ,  E. Haslam
Publisher:   Springer Verlag GmbH
Imprint:   Springer Verlag GmbH
Volume:   v.41
Weight:   0.860kg
ISBN:  

9783211816905


ISBN 10:   3211816909
Pages:   384
Publication Date:   June 1982
Audience:   College/higher education ,  Professional and scholarly ,  Undergraduate ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   Out of stock   Availability explained
The supplier is temporarily out of stock of this item. It will be ordered for you on backorder and shipped when it becomes available.

Table of Contents

The Metabolism of Gallic Acid and Hexahydroxydiphenic Acid in Higher Plants..- 1. Polyphenol Biosynthesis in Higher Plants - An Overview.- 2. Metabolites of Gallic Acid.- 2.1 Simple Esters - Occurrence and Structural Analysis.- 2.2 Depside Metabolites - Group A.- 2.3 Metabolites Formed by Oxidative Coupling of Galloyl Esters - Groups B and C.- 2.3.1 Hexahydroxydiphenoyl Esters.- 2.3.2 Dehydrohexahydroxydiphenoyl and Isohexahydroxydiphenoyl Esters..- 2.3.3 Hexahydroxydiphenoyl Metabolites - Group B.- 2.3.4 Hexahydroxydiphenoyl Metabolites - Group C.- 3. The Ellagitannins.- 4. Postscript.- References.- The Direct Biomimetic Synthesis, Structure and Absolute Configuration of Angular and Linear Condensed Tannins..- I. Introduction.- II. Bonding Positions at Nucleophilic Centres.- III. Conditions for Interflavanoid Bonding. Stereochemical Course of the Reaction. Chiroptical Method for Determining the Absolute Configuration at C-4.- IV. Direct Biomimetic Synthesis of Biflavanoids.- V. Direct Biomimetic Synthesis of Angular Triflavanoids.- VI. Biflavanoids and a Linear Triflavanoid with Terminal 3,4-Diol Function.- VII. Composition of the Metabolic Pool and Condensation Aptitudes of Tannin Precursors.- References.- Streptonigrin.- I. Introduction.- II. Isolation and Structure.- III. Structure Activity Relationships and Mechanism of Action.- IV. Biosynthesis.- V. Synthetic Studies.- References.- The Pyrrolizidine Alkaloids.- I. Introduction.- II. The Necine Bases.- 1. Structure and Stereochemistry.- a) 1-Hydroxymethylpyrrolizidines.- b) Pyrrolizidine Diols.- c) Pyrrolizidine Triols.- d) Dihydropyrrolizines.- 2. Synthesis of Necine Bases.- III. The Necic Acids.- 1. C6-Acids - Strigosic Acid.- 2. C8-Acids.- a) (-)-Curassavic Acid.- b) Crispatic Acid and Stereoisomers.- c) Monocrotalic Acid.- d) Latifolic Acid.- e) ?- and ?-Retusanecic Acids.- 3. C9-Acids.- 4. C10-Acids.- a) Retusaminic Acid.- b) Syneilesinolides A-C.- c) Ligularidenecic Acid.- d) Crotaverric Acid.- e) Petasinecic Acid.- f) cis-Nemorensic Acid.- 5. Orchid Acids.- IV. The Pyrrolizidine Alkaloids.- 1. Analytical Methods.- 2. Spectroscopy.- 3. Synthesis.- V. Pyrrolizidine Derivatives in the Lepidoptera.- VI. Biosynthesis.- 1. Necine Bases.- 2. Necic Acids.- VII. Pharmacology.- VIII. Table 1. List of Plant Genera Containing Pyrrolidine Alkaloids.- Table 2. Alkaloid Content of Plant Species Which Have Been Investigated.- Table 3. The Structures of the Pyrrolizidine Alkaloids.- References.- Addendum.- Alkaloids of Neotropical Poison Frogs (Dendrobatidae).- I. Introduction.- II. Batrachotoxins.- A. Structures.- B. Syntheses.- C. Biological Activity.- III. Pumiliotoxin-C Class (cis-decahydroquinolines).- A. Structures.- B. Syntheses.- C. Biological Activity.- IV. Histrionicotoxins.- A. Structures.- B. Syntheses.- C. Biological Activity.- V. Gephyrotoxins.- A. Structures.- B. Syntheses.- C. Biological Activity.- VI. Pumiliotoxin-A Class.- A. Structures.- B. Syntheses.- C. Biological Activity.- VII. Other Alkaloids.- A. Structures, Properties, and Occurrence.- References.- Author Index.

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