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Author:   Walther Grot (Ion Power, Inc. (former DuPont), Delaware, U.S.A.)
Publisher:   William Andrew Publishing
Imprint:   William Andrew Publishing
Edition:   2nd edition
Dimensions:   Width: 15.20cm , Height: 2.80cm , Length: 22.90cm
Weight:   0.570kg
ISBN:  

9781437744576

ISBN 10:   1437744575
Pages:   312
Publication Date:   29 July 2011
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

1 Introduction 1.1 Polymers 1.2 Physical Shapes 1.3 References 2 History 2.1 References 3 Manufacture 3.1 Introduction 3.2 Perfluorinated Ionomers 3.3 Polymerization 3.4 Fabrication 3.5 Hydrolysis and Acid Exchange 3.6 Finishing and Testing 3.7 Liquid Compositions 3.8 Fluorinated Ionomers with Phosphonic or Sulfonyl Imide Functional Groups 3.9 Partially Fluorinated Ionomers 3.10 Composite Materials of Ionomers and Inorganic Oxides 3.11 Composite Materials of Ionomers and a Porous Matrix 3.12 Remanufactured Membranes 3.13 References 4 Properties 4.1 Properties of the Precursor Polymers 4.2 Properties of the Ionic Forms 4.3 Morphology 4.4 Transport Properties 4.5 Optical Properties 4.6 Thermal Properties 4.7 Stability 4.8 References 5 Applications 5.1 Electrolysis 5.2 Sensors and Actuators 5.3 Dialysis 5.4 Gas and Vapor Diffusion 5.5 Protective Clothing 5.6 Catalysis 5.7 References 6 Fuel Cells and Batteries 6.1 Introduction 6.2 Operating Parameters 6.3 Ionomer Stability 6.4 Direct Methanol Fuel Cells (DMFCs) 6.5 Manufacture of MEAs 6.6 Rechargeable Flow Through Batteries 6.7 References 6.8 Further Reading 7 Commercial Membrane Types 7.1 Unreinforced Perfluorinated Sulfonic Acid Films 7.2 Reinforced Perfluorinated Membranes 8 Economic Aspects 8.1 Chlor-Alkali Cells 8.2 Fuel Cells 8.3 References 9 Experimental Methods 9.1 Infrared Spectra 9.2 Hydrolysis, Surface Hydrolysis and Staining 9.3 Other Reactions of the Precursor Polymer 9.4 Ion Exchange Equilibrium 9.5 Determination of EW by Titration or Infrared Analysis 9.6 Determining Melt Flow 9.7 Distinguishing the Precursor Polymer from Various Ionic Forms 9.8 Fenton’s Test for Oxidative Stability 9.9 Examination of a Membrane 9.10 Determining the Permselectivity 9.11 Measuring Pervaporation Rates 9.12 Simple Electrolytic Cells 9.13 References 10 Heat Sealing and Repair 10.1 Reference 11 Handling and Storage 11.1 Handling the Film 11.2 Pretreatment 11.3 Installation 11.4 Sealing and Gasketing 12 Toxicology, Safety and Disposal 12.1 Toxicology 12.2 Safety 12.3 Disposal 12.4 References Appendix A A Chromic Acid Regeneration System Appendix B Laboratory Chlor-alkali Cell Appendix C Solution Cast Nafion Film Appendix D Plastic-Based Bipolar Plates Suppliers and Resources Glossary and Web Sites Index

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