|
![]() |
|||
|
||||
OverviewThis volume provides a critical description of the methods used to probe the energetics of organic free radicals, including methods in: gas-phase and in solution, appearance energy measurements, photoacoustic calorimetry, electrochemical techniques and theoretical calculations. It also offers a critical review of the currently available data. This text is primarily directed at researchers and graduate/advanced undergraduate students in organic chemistry and biochemistry, but it is also intended to be of use as a reference source for food scientists, medicinal chemists, catalysis and surface scientists, fuel and combustion chemists, and chemical engineers. Full Product DetailsAuthor: José A. Martinho Simões , Joel F. Liebman , A. GreenbergPublisher: Chapman and Hall Imprint: Chapman and Hall Edition: 1996 ed. Volume: 4 Dimensions: Width: 15.20cm , Height: 1.90cm , Length: 22.80cm Weight: 0.710kg ISBN: 9780751403787ISBN 10: 0751403784 Pages: 320 Publication Date: 30 April 1996 Audience: College/higher education , Professional and scholarly , Postgraduate, Research & Scholarly , Professional & Vocational Format: Hardback Publisher's Status: Active Availability: In Print ![]() This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us. Table of Contents1 Free Radical Reactions.- 2 Heats of Formation of Organic Free Radicals by Kinetic Methods.- 3 Thermochemical Data for Free Radicals From Studies of Ions.- 4 Theoretical Studies of the Energetics of Radicals.- 5 Photoacoustic Calorimetry of Radicals and Biradicals.- 6 A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics.- 7 Resonance and 1,2-Rearrangements in Radicals: From Alkyl Radicals to Alkylcobalamins.- 8 Solvent Effects in the Reactions of Neutral Free Radicals.Reviews`...an important aid for anyone involved in mechanistic studies or synthetic work using free radicals. The tables of thermochemical data and the descriptions of the methods used to determine them will enable the reader to quickly gain an appreciation of the factors affecting the quality of such data.' Angewandte Chemie '...an important aid for anyone involved in mechanistic studies or synthetic work using free radicals. The tables of thermochemical data and the descriptions of the methods used to determine them will enable the reader to quickly gain an appreciation of the factors affecting the quality of such data.' Angewandte Chemie Author InformationTab Content 6Author Website:Countries AvailableAll regions |