Overview

The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dAC*, and ACAC* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy. Consequences of spin-orbit coupling, zero-field splittings, spin-lattice relaxations, chromophore-matrix interactions, Herzberg-Teller/Franck-Condon activities, and localization/delocalization properties are treated.

Full Product Details

Author:   Hartmut Yersin ,  T. Azumi ,  H.B. Gray ,  W. Humbs
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   Softcover reprint of the original 1st ed. 1997
Volume:   191
Dimensions:   Width: 15.50cm , Height: 1.40cm , Length: 23.50cm
Weight:   0.454kg
ISBN:  

9783642083129

ISBN 10:   3642083129
Pages:   262
Publication Date:   01 December 2010
Audience:   Professional and scholarly ,  Professional and scholarly ,  Professional & Vocational ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

Spectroscopy of the spin sublevels of transition metal complexes.- Magnetic and spectroscopic properties of Os2(O2CR)4Cl2. Evidence for a 3(?*?*) ground state.- Luminescence and absorption studies of transition metal ions in host crystals, pure crystals and surface environments.- Angular overlap model applied to transition metal complexes and dN-ions in oxide host lattices.- Characterization of excited electronic and vibronic states of platinum metal compounds with chelate ligands by highly frequency-resolved and time-resolved spectra.

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