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Author:   W. Keim
Publisher:   Springer
Imprint:   Kluwer Academic Publishers
Edition:   1983 ed.
Volume:   4
Dimensions:   Width: 15.50cm , Height: 1.90cm , Length: 23.50cm
Weight:   1.410kg
ISBN:  

9789027715272

ISBN 10:   9027715270
Pages:   314
Publication Date:   30 June 1983
Audience:   College/higher education ,  Professional and scholarly ,  Postgraduate, Research & Scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

Homogeneous Carbon Monoxide Hydrogenation.- 1. Stoichiometric CO Reduction (Model Reactions).- 2. Catalytic Homogeneous Reduction of Carbon Monoxide.- References.- FischerTropsch Synthesis.- 1. Introduction.- 2. Historic Developments in Heterogeneous Carbon Monoxide Hydrogenation.- 3. Technical Realization of the Fischer-Tropsch Synthesis.- 4. Basic Features of the Fischer-Tropsch Reaction.- 5. Product Selectivity Control.- 6. Mechanistic Considerations.- 7. Conclusions.- References.- Methanol Building Block for Chemicals.- 1. Mechanism of CO Reduction to Methanol.- 2. Future Use of Methanol.- References.- The Homologation of Methanol.- 1. Introduction.- 2. Cobalt-Catalyzed Methanol Homologation.- 3. Other Catalyst Metals.- 4. Conclusions.- References.- Hydroformylation and Carbonylation Reactions.- 1. Hydroformylation and Carbonylation of Unsaturated Organic Substrates.- 2. Carbonylation Under Oxidative Conditions.- References.- Activation of Carbon Dioxide via Coordination to Transition Metal Complexes.- 1. Introduction.- 2. Insertion of Carbon Dioxide into Transition Metal Complexes.- 3. Transition Metal-Catalyzed Syntheses Involving Carbon Dioxide.- 4. Deoxygenation of CO2.- 5. Dimerization of CO2.- 6. Carbon Dioxide as a Cocatalyst in Homogeneous Catalysis.- 7. Conclusions.- 8. Glossary of Nonstandard Abbreviations.- References.- Hydrocyanation.- 1. Introduction.- 2. Reaction of HCN with Multiple Bonds.- 3. Applications of HCN in Organic Chemistry Other than Addition to Multiple Bonds.- 4. Physiological Properties of HCN and Safety.- References.- Methane.- 1. Methane.- 2. Alkanes.- References.- Carbenes.- 0. Introduction.- 1. The Structure of Carbenes.- 2. Reactivity of Carbenes.- 3. Regioselectivity of Carbenes.- 4. The Relative Stability of Spin States.- 5. The Generation of Carbenes.- 6. Carbene Metal Complexes.- 7. The Structure of Carbenoids.- 8. Carbenes in Fine-Chemical Synthesis.- 9. Carbenoids in Fine-Chemicals Synthesis.- 10. Mechanisms of Copper-Catalyzed Carbene Reactions.- 11. Catalysis by Metals Other than Copper.- 12. Synthetic Applications of Group VIII Transition Metal Complexes.- 13. Carbenoids in Industrial Process.- References.

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