Overview

This text commemorates the 50th anniversary of the calixarenes. In 1944, Zinke and Ziegler proposed a cyclotetrameric structure for an oligomer extracted from the condensation product mixture obtained by reacting p-tert-butyl phenol with formaldehyde in the presence of sodium hydroxide. In the mid-1990's calixarenes are the basis of many different areas of chemical research. This book does not provide an overview of all the developments, but is a review of some of the highlights.

Full Product Details

Author:   Jacques Vicens ,  M.-Z. Asfari ,  J. Harrowfield
Publisher:   Springer
Imprint:   Springer
Edition:   Reprinted from JOURNAL OF INCLUSION PHENOMENA, 19:1-4
Dimensions:   Width: 17.00cm , Height: 2.30cm , Length: 24.40cm
Weight:   1.710kg
ISBN:  

9780792333937

ISBN 10:   0792333934
Pages:   418
Publication Date:   31 March 1995
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

Introducing Paper.- The Early History of Calixarene Chemistry.- Review Articles.- Inherently Chiral Calixarenes.- The Design of Cone-Fixed Calix[4]arene Analogs by Taking syn-[2.n]Metacyclophanes as a Building Block.- Conformational Properties of Calix[4]naphthalenes.- The Host-Guest Chemistry of Resorcinarenes.- Synthesis and Properties of Pyridinocalixarenes.- Calixarenes with Nitrogen or Phosphorus Substituents on the Lower Rim.- Homocalixarenes and Homocalixpyridines.- Calixcrowns and Related Molecules.- Calixarene-Based Sensing Agents.- Proximally Functionalized Cavitands and Synthesis of a Flexible Hemicarcerand.- Synthesis and Properties of N-Substituted Azacalix[n]arenas.- Arranging Coordination Sites around Cyclotriveratrylene.- X-Ray Crystallographic Studies of Tricarbonylchromium Complexes of Calix[4]arene Conformers on an Unusual Conformation which Appears in Cone Conformers.- Preparation, Structure and Stereodynamics of Phosphorus-Bridged Calixarenes.- Inclusion of Quaternary Ammonium Compounds by Calixarenes.- Calixarenes: Structure of an Acetonitrile Inclusion Complex and Some Metal Rimmed Derivatives.- Synthesis, Characterization, and X-Ray Structure of l,2-Bis-crown-5-calix[4]arene. Modeling of Metal Complexation.- Complexation Properties and Characterization of Four Conformers of a [2.1.2.1]Metacyclophane.- Synthesis and Ion Selectivity of Macrocyclic Metacyclophanes Analogous to Spherand-Type Calixarenes.- Polymeric Membrane Sodium-Selective Electrodes Based on Calix[4]arene Ionophores.- Recognition by New Diester and Diamide-Calix[4]arene Diquininones and a Diamide-Benzo-15-Crown-5 Calix[4]arene.- The Complexation of Ferrocene Derivatives by a Water-Soluble Calix[6]arene.- Thermodynamic and Electrochemical Aspects of p-tert-butyl-calix(n)arenes (n =4, 6, 8) and Their Interactions with Amines.- Advanced Materials.- Liquid Crystalline Calixarenes.- Nuclear Waste Treatment by Means of Supported Liquid Membranes Containing Calixcrown Compounds.- Conference Diary.- Author Index.

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