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OverviewDrawing on reports published since 2005, this book is the only one to cover the latest advances concerning the properties of calixarenes of various structures, while highlighting their future applications in science and new technologies. Clearly divided into three main topic areas, this monograph deals with the synthesis of new calixarenes and their functionalization, properties and applications of such related compounds as resorcinarenes, cavitands, and capsules, as well as practical applications of the species considered. Full Product DetailsAuthor: Wanda Sliwa (Jan Dlugosz University, Czestochowa, Poland) , Cezary Kozlowski (Jan Dlugosz University, Czestochowa, Poland)Publisher: Wiley-VCH Verlag GmbH Imprint: Blackwell Verlag GmbH Dimensions: Width: 17.70cm , Height: 2.00cm , Length: 24.50cm Weight: 0.748kg ISBN: 9783527322633ISBN 10: 3527322639 Pages: 324 Publication Date: 18 February 2009 Audience: Professional and scholarly , Professional & Vocational Format: Hardback Publisher's Status: Out of Print Availability: In Print ![]() Limited stock is available. It will be ordered for you and shipped pending supplier's limited stock. Table of ContentsIntroduction PART I: General Characteristics of Calixarenes REACTIVITY OF CALIXARENES Functionalization of the Narrow Rim Functionalization of the Wide Rim Functionalization of Both Rims Bridging of Calixarenes Other Reactions of Calixarenes PHYSICOCHEMICAL PROPERTIES OF CALIXARENES Selected Physicochemical Properties of Calixarenes Crystallographic Studies of Calixarenes Calculations of Calixarene Structures CHIRAL CALIXARENES CALIXARENE ASSEMBLIES THE ROLE OF CALIXARENES IN BIOLOGICAL PROCESSES Antibacterial and Antiviral Calixarenes Transmembrane Systems of Biologically Active Calixarenes Calixarenes Binding Proteins, Nucleotides, and Nucleic Acids Calixarenes of other Biological Activities APPLICATIONS OF CALIXARENES Calixarene Sensors Calixarene Catalysts Nanoparticles Coated with Calixarenes Other Applications of Calixarenes PART II: Inclusion Complexes of Calixarenes and Calixcrowns INCLUSION COMPLEXES OF CALIXARENES WITH NEUTRAL AND CHARGED SPECIES Inclusion Complexes of Calixarenes with Neutral Molecules Inclusion Complexes of Calixarenes with Anions Inclusion Complexes of Calixarenes with Ion Pairs Inclusion Complexes of Calixarenes with Cations Inclusion Complexes of Calixarenes with Fullerenes Inclusion Complexes of Calixarenes with Gases INCLUSION COMPLEXES OF CALIXARENES WITH METAL IONS Inclusion Complexes of Calixarenes with Alkali and Transition Metal Ions Inclusion Complexes of Calixarenes with Lanthanides and Actinides Use of Calixarenes in the Solvent Extraction of Metal Ions Calixarenes as Sensors for Metal Ions Calixarene Metal Complexes as Catalysts INCLUSION COMPLEXES OF CALIXCROWNS WITH METAL IONS Inclusion Complexes of Calixcrowns with Alkali Metal Ions Use of Calixcrowns in the Solvent Extraction of Metals Calixcrowns as Sensors for Metal Ions PART III: Supramolecular Calixarene Structures and Related Systems CAVITANDS Simple Cavitands Deep Cavitands CAPSULES Calixarene-Based Capsules Cavitand-Based Capsules CALIXARENE NANOTUBES AND HELICES Calixarene Nanotubes Calixarene Helices CALIXARENE SUPRAMOLECULAR ASSEMBLIES Calixarene Assemblies with TTF Units Calixarene Assemblies with Polymers Calixarene Molecular Machines Calixarene Molecular Actuators PART IV: Resorcinarenes RESORCINARENES Synthesis of Resorcinarenes Reactivity of Resorcinarenes Physicochemical Properties of Resorcinarenes Cavitands Capsules Inclusion Complexes of Resorcinarenes The Role of Resorcinarenes in Biological Processes Applications of ResorcinarenesReviewsAuthor InformationWanda Sliwa graduated from Wroclaw University of Technology, Poland, where she received her MSc and PhD, and began work as an assistant professor, before becoming an associate professor. After a year of research at Universite Paul Sabatier a Toulouse, France, she moved to Jan Dlugosz University of Czestochowa, Poland, where she has been Professor of Chemistry since 1990, as well as being a vice-rector, head of the Organic Chemistry Department and director of the Institute of Chemistry. She has one book and 14 monographs, around 300 papers and ten patents to her name, and has received several awards for scientific and pedagogical achievements. Professor Sliwa's research concerns azaaromatic compounds and supramolecular chemistry. Cezary Kozlowski received his MSc from Jan Dlugosz University (former Pedagogical University) of Czestochowa in 1993, and subsequently worked at the Technical University of Czestochowa in the Chemistry Department as a research and teaching assistant until 2000, when he earned his PhD. Since 2001 he has been working at Jan Dlugosz University of Czestochowa in the Institute of Chemistry and Environmental Protection. He has published 30 papers in refereed journals, 50 communications to scientific meetings and co-authored a book. Dr Kozlowski's research interests focus on the application of macrocyclic ligands as carriers for transport across liquid membranes for the recovery of metal ions from waste water. Tab Content 6Author Website:Countries AvailableAll regions |