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Author:   B. Bosnich
Publisher:   Springer
Imprint:   Kluwer Academic Publishers
Edition:   1986 ed.
Volume:   103
Dimensions:   Width: 15.60cm , Height: 1.20cm , Length: 23.40cm
Weight:   0.422kg
ISBN:  

9789024732593

ISBN 10:   902473259
Pages:   172
Publication Date:   30 November 1985
Audience:   College/higher education ,  Professional and scholarly ,  Postgraduate, Research & Scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Temporarily unavailable  
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Table of Contents

1 - General Principles.- 1. Catalysis.- 2. Turnover Limiting Step.- 3. Origin of Catalysis.- 4. Catalytic Cycles.- 5. Classification of Catalysts.- 6. Asymmetric Synthesis.- 7. Asymmetric Discrimination.- 8. Reactant Control and Product Control in the Enantio- selective Step.- References.- 2 - Carbon-Hydrogen Bond Formation.- 1. Asymmetric Catalytic Hydrogenation.- References.- 2. Asymmetric Hydrogenation of Ketones.- References.- 3. Asymmetric Double Bond Migration.- References.- 4. Asymmetric Hydrosilation.- References.- 3 - Carbon-Carbon Bond Formation.- 1. Hydroformylation.- References.- 2. Asymmetric Hydrocarboxylation.- References.- 3. Asymmetric Hydrocyanation.- References.- 4. Asymmetric Allylic Alkylation.- References.- 5. Asymmetric Grignard Cross-Coupling.- References.- 6. Asymmetric Cyclopropanation.- References.- 7. Catalytic Asymmetric Codimerization.- References.- 1. Catalytic Asymmetric Cyclodimerization, Skeletal Rearrangement and Telomerization and Asymmetric [3+2]-Cycloaddition.- References.- 2. Asymmetric Catalyzed Diels-Alder Reaction.- References.- 4 - Asymmetric Oxidation.- 1. Asymmetric Epoxidation.- References.- 2. Asymmetric Oxidation of Sulfides.- References.- 5 - Heterogeneous and Polymer Supported Catalysts.- 1. Impregnated Heterogeneous Catalysts.- 2. Electrochemical Asymmetric Reduction.- References.- 3. Polymer Supported Catalysts.- References.- 6 - Asymmetric Catalysis by Biochemical Systems.- (i) Classification of Enzyme Reactions.- (ii) Coenzymes.- (iii) Fermentative vs. Enzymic Processes.- (iv) Enantiotopic Group Differentiation.- (v) Immobilized Enzymes and Cells.- (vi) Range of Applicability of Enzymes.- References.- 7 - Economic Significance of Asymmetric Catalysis.- 1. Economic Advantages of Asymmetric Synthesis.- 2. Intramolecular Aldol Condensations of Hajos and Eder.- References.- 3. Potential Chirons of Economic Importance.- 4. Examples of Target Molecules which have been more Economically Prepared by Asymmetric Synthesis.- 8 - Future Trends.- 1. Enzymes and Microbes.- 2. Inorganic Systems.- 3. Purely Organic Catalysts.

Reviews

... presents an overview of the state of the art of this important subject (as of early 1984). It would be appropriate to any graduate level course in Organometallic, Catalytic, or Synthetic Chemistry. It would also serve as an selective primer for anyone considering serious research in this rapidly expanding field.' Journal of the American Chemical Society, 108:18 (1986) ... presents an overview of the state of the art of this important subject (as of early 1984). It would be appropriate to any graduate level course in Organometallic, Catalytic, or Synthetic Chemistry. It would also serve as an selective primer for anyone considering serious research in this rapidly expanding field.' Journal of the American Chemical Society, 108:18 (1986)

... presents an overview of the state of the art of this important subject (as of early 1984). It would be appropriate to any graduate level course in Organometallic, Catalytic, or Synthetic Chemistry. It would also serve as an selective primer for anyone considering serious research in this rapidly expanding field.' Journal of the American Chemical Society, 108: 18 (1986)

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