Overview

Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers which contain metal cations and the structure-building organic ""linker"" units. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. Thousands of organic compounds and, in particular, aromatic and heterocyclic compounds are widely used as feedstock for industrial chemical synthesis, as fine chemicals, major components of liquid fossil fuels, dyestuffs, industrial solvents, agricultural chemicals, medicinal drugs, pharmaceuticals and personal care products (PPCPs), and active pharmaceutical ingredients (APIs). There is a strong interest towards synthesis, characterization and studies of both known and newly synthesized mesoporous MOFs for adsorption in solution to achieve the high adsorption capacity, selectivity, and the possibility of multiple regeneration of ""spent"" sorbent. This book covers experimental fundamental research on using mesoporous MOFs in emerging applications of major industrial, environmental and academic importance, especially purification of water and liquid fossil fuels and in advanced biomedical technologies.

Full Product Details

Author:   Alexander Samokhvalov
Publisher:   Taylor & Francis Ltd
Imprint:   CRC Press
Weight:   0.453kg
ISBN:  

9780367877873

ISBN 10:   0367877872
Pages:   216
Publication Date:   12 December 2019
Audience:   College/higher education ,  Undergraduate ,  Postgraduate, Research & Scholarly
Format:   Paperback
Publisher's Status:   Active
Availability:   In Print  
This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us.

Table of Contents

Contents Preface List of Illustrations Chapter 1 – Introduction Chapter 2 - Post-synthetic Modifications of Mesoporous MOFs for Adsorption-based Applications 2.1 Post-synthetic Modifications of MIL-101 for Adsorption and Catalysis in Solution 2.2 Post-synthetic Modifications of MIL-100 for Adsorption and Catalysis in Solution 2.3 The PSM of Mesoporous MOFs other than MIL-101 and MIL-100 for Applications Based on Adsorption Chapter 3 - Mechanistic Studies of Activation of Mesoporous MOFs Chapter 4 - Stability of Mesoporous MOFs in Water 4.1 Water Stability of MIL-101(Cr) 4.2 Water Stability of Chemically Modified MIL-101(Cr) 4.3 Water Stability of MIL-101(Fe), MIL-101(Al) and MIL-101(V) 4.4 Water Stability of MIL-100(Fe) 4.5 Water Stability of MIL-100(Cr) 4.6 Water Stability of MIL-100(Al) 4.7 Water Stability of Chemically Modified MIL-100 4.8 Water Stability of Mesoporous MOFs other than MIL-101 and MIL-100 Chapter 5 - Adsorption of Organic Dyes by Mesoporous MOFs in Water 5.1 Adsorption of Cationic Dyes on MIL-101 5.2 Adsorption of Cationic Dyes on MIL-100 5.3 Adsorption of Anionic Dyes on MIL-101 5.4 Adsorption of Anionic Dyes on MIL-100 Chapter 6 - Adsorption of Biologically Active Compounds on Mesoporous MOFs in Water 6.1 Adsorption of Small Molecule Medicinal Drugs on MIL-101 6.2 Adsorption of Small Molecule Medicinal Drugs on MIL-100 6.3 Adsorption of Biologically Active Organic Compounds on MIL-100, MIL-101 and Similar MOFs 6.4 Adsorption of Large Molecule Biologically Active Compounds on Miscellaneous Mesoporous MOFs Chapter 7 - Adsorption of Miscellaneous Organic Compounds in Water Chapter 8 - Adsorption of Inorganic Ions on Mesoporous MOFs from Water Chapter 9 - Adsorption of Aromatic

Reviews

Author Information

Alexander Samokhvalov received his BSc and MSc in chemistry at the Novosibirsk State University in Russia. He earned his PhD in chemistry at the Weizmann Institute of Science in Israel. He had spent a few years of postdoctoral training in the United States at Duke University, UC Santa Barbara, and Auburn University in Alabama. Since 2010, he is an assistant professor of physical chemistry at the Chemistry Department of Rutgers University. His research interests are in mechanistic studies of adsorption by metal–organic frameworks (MOFs) in solution.

Tab Content 6

Author Website:  

Customer Reviews

Recent Reviews

No review item found!

Add your own review!

Countries Available

All regions